EL3306 ELECTROCHEMICAL REACTION ENGINEERING SYLLABUS | ANNA UNIVERSITY B.TECH. CHEMICAL AND ELECTROCHEMICAL ENGINEERING 5TH SEMESTER SYLLABUS REGULATION 2008 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY FIFTH SEMESTER B.TECH. CHEMICAL AND ELECTROCHEMICAL ENGINEERING DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS, IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI,TIRUNELVELI,COIMBATORE), 2008 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009
EL3306 ELECTROCHEMICAL REACTION ENGINEERING L T P C
3 1 0 4
UNIT I CURRENT-VOLTAGE RELATIONSHIPS & ESTIMATION OF MASS
TRANSFER CO-EFFICIENT 9
A general view of electrolytic processes; current-voltage relationships in electrolytic reactors;
the limiting current plateau; mass & energy balance, and efficiency in electrochemical
reactors. The estimation of mass transport coefficients at commonly occurring electrodes.
The estimation of mass transport coefficients under enhanced convection conditions.
UNIT II PLUG FLOW & CSTER SYSTEMS MODEL 9
A general view of plug flow model of electrolytic reactors: plug flow model of electrochemical
reactors employing parallel plate reactor; Plug flow model under constant mass flux
conditions; PFM analysis with electrolyte recycling PFM and real electrochemical reactors.
General view of simple CSTER systems; CSTER in cascades; CSTER analysis of batch
electrochemical reactors, CSTER analysis of semi-continuous electrochemical reactors;
CSTER analysis of electrolyte recycling; Batch reactor combined with electrolyte recycling.
UNIT III THERMAL BEHAVIOR OF REACTORS 9
General aspects of thermal behavior in electrochemical reactor. Thermal behavior under
CSTER conditions. The estimation of heat losses; the thermal behavior under PFR
conditions; Thermal behavior of batch electrochemical reactors.
UNIT IV CONVECTIVE DIFFUSION EQUATION & CURRENT DISTRIBUTION 9
Convective diffusion equation and migration effects –derivation of convective diffusion
equation theory – scope and limitation – migration effects – Electroneutrality conditions –
supporting electrolyte effect – fundamental of Nernst layer model – Estimation of true
limiting current
UNIT V DISPERSION MODELS & OPTIMIZATION OF ELECTROCHEMICAL
REACTOR 9
General aspects of dispersion models-tracer input signal/output signal - axial dispersion in
electrochemical reactors - axial dispersion and reactor performance - axial dispersion
analysis via tank-in-series model - general notions on optimization of electrochemical reactor
– elementary process optimization – IBL formula – optimization of electro refining process –
Jaskula formula – optimization of a general electrolytic process – The Beck formula.
L : 45 T : 15 TOTAL : 60 PERIODS
TEXT BOOK
1. T.Z.Fahidy, “Principles of Electrochemical Reactor Analysis”, Elsevier, 1985.
REFERENCE
1. K.Scott, “Electrochemical Reaction Engineering”, Academic Press, 1991
EL3306 ELECTROCHEMICAL REACTION ENGINEERING L T P C
3 1 0 4
UNIT I CURRENT-VOLTAGE RELATIONSHIPS & ESTIMATION OF MASS
TRANSFER CO-EFFICIENT 9
A general view of electrolytic processes; current-voltage relationships in electrolytic reactors;
the limiting current plateau; mass & energy balance, and efficiency in electrochemical
reactors. The estimation of mass transport coefficients at commonly occurring electrodes.
The estimation of mass transport coefficients under enhanced convection conditions.
UNIT II PLUG FLOW & CSTER SYSTEMS MODEL 9
A general view of plug flow model of electrolytic reactors: plug flow model of electrochemical
reactors employing parallel plate reactor; Plug flow model under constant mass flux
conditions; PFM analysis with electrolyte recycling PFM and real electrochemical reactors.
General view of simple CSTER systems; CSTER in cascades; CSTER analysis of batch
electrochemical reactors, CSTER analysis of semi-continuous electrochemical reactors;
CSTER analysis of electrolyte recycling; Batch reactor combined with electrolyte recycling.
UNIT III THERMAL BEHAVIOR OF REACTORS 9
General aspects of thermal behavior in electrochemical reactor. Thermal behavior under
CSTER conditions. The estimation of heat losses; the thermal behavior under PFR
conditions; Thermal behavior of batch electrochemical reactors.
UNIT IV CONVECTIVE DIFFUSION EQUATION & CURRENT DISTRIBUTION 9
Convective diffusion equation and migration effects –derivation of convective diffusion
equation theory – scope and limitation – migration effects – Electroneutrality conditions –
supporting electrolyte effect – fundamental of Nernst layer model – Estimation of true
limiting current
UNIT V DISPERSION MODELS & OPTIMIZATION OF ELECTROCHEMICAL
REACTOR 9
General aspects of dispersion models-tracer input signal/output signal - axial dispersion in
electrochemical reactors - axial dispersion and reactor performance - axial dispersion
analysis via tank-in-series model - general notions on optimization of electrochemical reactor
– elementary process optimization – IBL formula – optimization of electro refining process –
Jaskula formula – optimization of a general electrolytic process – The Beck formula.
L : 45 T : 15 TOTAL : 60 PERIODS
TEXT BOOK
1. T.Z.Fahidy, “Principles of Electrochemical Reactor Analysis”, Elsevier, 1985.
REFERENCE
1. K.Scott, “Electrochemical Reaction Engineering”, Academic Press, 1991
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