IC9312 ADVANCED THERMODYNAMICS SYLLABUS | ANNA UNIVERSITY ME ENERGY ENGINEERING 1ST SEM SYLLABUS REGULATION 2009 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY FIRST SEMESTER ME ENERGY ENGINEERING DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS,EXAM PORTIONS,QUESTION BANK,PREVIOUS YEAR QUESTION PAPERS,MODEL QUESTION PAPERS, CLASS NOTES, IMPORTANT 2 MARKS, 8 MARKS, 16 MARKS TOPICS. IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI, TIRUNELVELI,COIMBATORE), 2009 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009
IC9312 ADVANCED THERMODYNAMICS L T P C
3 1 0 4
UNIT I AVAILABILITY ANALYSIS AND THERMODYNAMIC
PROPERTY RELATIONS 10
Reversible work - availability - irreversibility and second – law efficiency for a closed
system and steady – state control volume. Availability analysis of simple cycles.
Thermodynamic potentials. Maxwell relations. Generalized relations for changes in
entropy - internal energy and enthalpy - generalized relations for Cp and CV Clausius
Clayperon equation, Joule – Thomson coefficient.Bridgeman tables for
thermodynamic relations.
UNIT II REAL GAS BEHAVIOUR AND MULTI – COMPONENT
SYSTEMS 10
Different equations of state – fugacity – compressibility - principle of corresponding
States - Use of generalized charts for enthalpy and entropy departure - fugacity
coefficient,Lee – Kesler generalized three parameter tables. Fundamental property
relations for systems of variable composition.Partial molar properties.Real gas
mixtures - Ideal solution of real gases and liquid - activity - equilibrium in multi phase
systems - Gibbs phase rule for non – reactive components.
UNIT III CHEMICAL THERMODYNAMICS AND EQUILIBRIUM 10
Thermochemistry - First law analysis of reacting systems - Adiabatic flame
temperature - entropy change of reacting systems - Second law analysis of reacting
systems - Criterion for reaction equilibrium.Equilibrium constant for gaseous
mixtures - evaluation of equilibrium composition.
UNIT IV STATISTICAL THERMODYNAMICS 8
Microstates and Macrostates - thermodynamic probability - degeneracy of energy
levels - Maxwell – Boltzman, Fermi – Diarc and Bose – Einstein statistics -
microscopic interpretation of heat and work, evaluation of entropy, partion function,
calculation of the Macroscopic properties from partition functions.
UNIT V IRREVERSIBLE THERMODYNAMICS 7
Conjugate fluxes and forces - entropy production Onsager’s reciprocity relations -
thermo – electric phenomena, formulations.
TOTAL (L – 45 + T – 15): 60 PERIODS
REFERENCES
1. Kenneth Wark Jt.m, Advanced Thermodynamics for Engineers, McGrew – Hill
Inc., 1995.
2. Bejan, A., Advanced Engineering Thermodynamics, John Wiley and Cons, 1988.
3. Holman, J.P., Thermodynamics, Fourth Edition, McGraw – Hill Inc., 1988.
4. Smith, J.M. and Van Ness., H.C., Introduction to Chemical Engineering
Thermodynamics, Fourth Edition, McGraw – Hill Inc., 1987.
5. Sonntag, R.E., and Van Wylen, G, Introduction to Thermodynamics, Classical
and Statistical Themodynamics, Third Edition, John Wiley and Sons, 1991.
6. Sears, F.W. and Salinger G.I., Thermodynamics, Kinetic Theory and Statistical
Thermodynamics, Third Edition, Narosa Publishing House, New Delhi, 1993.
7. DeHotf, R.T., Thermodynamics in Materials Science, McGraw – Hill Inc., 1993.
8. Rao, Y.V.C., Postulational and Statistical Thermodynamics, Allied Publisher
Limited, New Delhi, 1999.
IC9312 ADVANCED THERMODYNAMICS L T P C
3 1 0 4
UNIT I AVAILABILITY ANALYSIS AND THERMODYNAMIC
PROPERTY RELATIONS 10
Reversible work - availability - irreversibility and second – law efficiency for a closed
system and steady – state control volume. Availability analysis of simple cycles.
Thermodynamic potentials. Maxwell relations. Generalized relations for changes in
entropy - internal energy and enthalpy - generalized relations for Cp and CV Clausius
Clayperon equation, Joule – Thomson coefficient.Bridgeman tables for
thermodynamic relations.
UNIT II REAL GAS BEHAVIOUR AND MULTI – COMPONENT
SYSTEMS 10
Different equations of state – fugacity – compressibility - principle of corresponding
States - Use of generalized charts for enthalpy and entropy departure - fugacity
coefficient,Lee – Kesler generalized three parameter tables. Fundamental property
relations for systems of variable composition.Partial molar properties.Real gas
mixtures - Ideal solution of real gases and liquid - activity - equilibrium in multi phase
systems - Gibbs phase rule for non – reactive components.
UNIT III CHEMICAL THERMODYNAMICS AND EQUILIBRIUM 10
Thermochemistry - First law analysis of reacting systems - Adiabatic flame
temperature - entropy change of reacting systems - Second law analysis of reacting
systems - Criterion for reaction equilibrium.Equilibrium constant for gaseous
mixtures - evaluation of equilibrium composition.
UNIT IV STATISTICAL THERMODYNAMICS 8
Microstates and Macrostates - thermodynamic probability - degeneracy of energy
levels - Maxwell – Boltzman, Fermi – Diarc and Bose – Einstein statistics -
microscopic interpretation of heat and work, evaluation of entropy, partion function,
calculation of the Macroscopic properties from partition functions.
UNIT V IRREVERSIBLE THERMODYNAMICS 7
Conjugate fluxes and forces - entropy production Onsager’s reciprocity relations -
thermo – electric phenomena, formulations.
TOTAL (L – 45 + T – 15): 60 PERIODS
REFERENCES
1. Kenneth Wark Jt.m, Advanced Thermodynamics for Engineers, McGrew – Hill
Inc., 1995.
2. Bejan, A., Advanced Engineering Thermodynamics, John Wiley and Cons, 1988.
3. Holman, J.P., Thermodynamics, Fourth Edition, McGraw – Hill Inc., 1988.
4. Smith, J.M. and Van Ness., H.C., Introduction to Chemical Engineering
Thermodynamics, Fourth Edition, McGraw – Hill Inc., 1987.
5. Sonntag, R.E., and Van Wylen, G, Introduction to Thermodynamics, Classical
and Statistical Themodynamics, Third Edition, John Wiley and Sons, 1991.
6. Sears, F.W. and Salinger G.I., Thermodynamics, Kinetic Theory and Statistical
Thermodynamics, Third Edition, Narosa Publishing House, New Delhi, 1993.
7. DeHotf, R.T., Thermodynamics in Materials Science, McGraw – Hill Inc., 1993.
8. Rao, Y.V.C., Postulational and Statistical Thermodynamics, Allied Publisher
Limited, New Delhi, 1999.
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