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PL9311 POLYMER CHEMISTRY SYLLABUS | ANNA UNIVERSITY MTECH POLYMER TECHNOLOGY 1ST SEM SYLLABUS REGULATION 2009 2011 2012-2013

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PL9311 POLYMER CHEMISTRY SYLLABUS | ANNA UNIVERSITY MTECH POLYMER TECHNOLOGY 1ST SEM SYLLABUS REGULATION 2009 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY FIRST SEMESTER M.TECH POLYMER TECHNOLOGY DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS,EXAM PORTIONS,QUESTION BANK,PREVIOUS YEAR QUESTION PAPERS,MODEL QUESTION PAPERS, CLASS NOTES, IMPORTANT 2 MARKS, 8 MARKS, 16 MARKS TOPICS. IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI, TIRUNELVELI,COIMBATORE), 2009 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009

PL9311 POLYMER CHEMISTRY L T P C
3 0 0 3
UNIT I FUNDAMENTALS OF POLYMERS 12
Basic concepts of polymer science – classification of polymers – Polymer microstructurechemical
structure and geometrical structure - ladder, star and honey- comb polymers –
interpenetrating networks –tacticity – crystalline and amorphous polymers- thermal
transitions–glass transition temperature(Tg) - heat distortion temperature.
UNIT II BIO AND INORGANIC POLYMERS 9
Naturally occurring polymers – starch, cellulose, polypeptides – modified cellulose polymers
– rayon, cellophane, cellulose acetate, butyrate and nitrate – ethyl cellulose – carboxy
methyl cellulose- organometallic polymers - co-ordination polymers - polyamides- Inorganic
polymers - phosphorous and nitrogen containing polymers – silicones.
UNIT III CHAIN POLYMERISATION 8
Kinetics and mechanism of free radical, cationic, anionic and coordination polymerisation –
stereo regular polymerization - chain transfer reaction and constant –Trommsdorff’s effect -
living polymers – Alfin catalysts – iniferters.
UNIT IV STEP GROWTH POLYMERISATION AND COPOLYMERIZATION 8
Kinetics of condensation polymerisation – copolymerisation – copolymer equation –
composition of copolymers by NMR, IR and UV spectra and chemical methods –monomer
reactivity ratios and their significance - metathetical, electrochemical and ring opening
polymerisations.
UNIT V MOLECULAR WEIGHT, SOLUBILITY AND FRACTIONATION OF
POLYMER 8
Molecular weight of polymers – number, weight and viscosity average molecular weights –
polydispersity - molecular weight distribution – determination of molecular weight by GPC
and viscometry – polymer dissolution - thermodynamics of polymer dissolution - solubility
parameter – fractionation of polymers - reactions of polymers - introduction of new functional
groups - cross linking, cyclisation and degradation reactions.
TOTAL: 45 PERIODS
REFERENCES
1. F.N. Billmayer, Text Book of Polymer Science, 3rd edition, John Wiley and sons, New
York, 2002.
2. V.R. Gowarikar, N.V.Viswanathan and Jayadev Sreedhav, Polymer Science, Wiley
Eastern Limited, Madras 2006.
3. R.J. Young, Introduction to Polymers, Chapman and Hall Ltd., London, 1999.
4. Gorge Odean – Principles of Polymerisation, 4th editon, Mc.Graw Hill Book
Company, New York.2004.
5. M.S.Bhatnagar, “ A Text Book of Polymers ( chemistry and Technology of polymers), Vol
I, II & III, 1st Edn., S.Chand and Company, Newdelhi, 2007.

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