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CH2043 POLYMER TECHNOLOGY SYLLABUS | ANNA UNIVERSITY BTECH CHEMICAL ENGINEERING 8TH SEMESTER SYLLABUS REGULATION 2008 2011 2012-2013

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CH2043 POLYMER TECHNOLOGY SYLLABUS | ANNA UNIVERSITY BTECH CHEMICAL ENGINEERING 8TH SEMESTER SYLLABUS REGULATION 2008 2011 2012-2013 BELOW IS THE ANNA UNIVERSITY 8TH SEMESTER B.TECH CHEMICAL ENGINEERING DEPARTMENT SYLLABUS, TEXTBOOKS, REFERENCE BOOKS,EXAM PORTIONS,QUESTION BANK,PREVIOUS YEAR QUESTION PAPERS,MODEL QUESTION PAPERS, CLASS NOTES, IMPORTANT 2 MARKS, 8 MARKS, 16 MARKS TOPICS. IT IS APPLICABLE FOR ALL STUDENTS ADMITTED IN THE YEAR 2011 2012-2013 (ANNA UNIVERSITY CHENNAI,TRICHY,MADURAI, TIRUNELVELI,COIMBATORE), 2008 REGULATION OF ANNA UNIVERSITY CHENNAI AND STUDENTS ADMITTED IN ANNA UNIVERSITY CHENNAI DURING 2009

CH2043 POLYMER TECHNOLOGY L T P C
3 0 0 3
UNIT I INTRODUCTION 6
History of Macromolecules – structure of natural products like cellulose, rubber,proteins
– concepts of macro molecules – Staudinger’s theory of macromolecules – difference
between simple organic molecules and macromolecules.
UNIT II ADDITION POLYMERIZATION 12
Chemistry of Olefins and Dienes – double bonds – Chemistry of free radicals –
monomers – functionality – Polymerization: Initiation – types of initiation – free radical
polymerization – cationic polymerization – anionic polymerization – coordination
polymerization – industrial polymerization – bulk, emulsion, suspension and solution
polymerization techniques – Kinetics – Copolymerization concepts.
UNIT III CONDENSATION POLYMERIZATION 9
Simple condensation reactions – Extension of condensation reactions to polymer
synthesis – functional group reactivity – polycondensation – kinetics of
polycondensation- Carother’s equation – Linear polymers by polycondensation –
Interfacial polymerization – crosslinked polymers by condensation – gel point.
UNIT IV MOLECULAR WEIGHTS OF POLYMERS 9
Difference in molecular weights between simple molecules and polymers – number
average and weight average molecular weights – Degree of polymerization and
molecular weight – molecular weight distribution – Polydispersity – molecular weight
determination. Different methods – Gel Permeation Chromatography – Osmometry,
Light Scattering.
UNIT V TRANSITIONS IN POLYMERS 9
First and second order transitions – Glass transition, Tg – multiple transitions in
polymers – experimental study – significance of transition temperatures – crystallinity in
polymers – effect of crystallization – in polymers – factors affecting crystallization crystal
nucleation and growth – relationship between Tg and Tm – Relationship between
properties and crystalline structure.
TOTAL : 45 PERIODS
77
REFERENCES
1. Billmeyer.F.W.,Jr, Text Book of Polymer Science, Ed. Wiley-Interscience, 1984.
2. Seymour.R.B., and Carraher.C.E., Jr., Polymer Chemistry, 2nd Ed., Marcel Dekker,
1988.
3. Gowariker.V.T., Viswanathan.N.V., and Sreedar.J., Polymer Science, Wiley Eastern
Ltd., 1988.
4. Joel,R.F; Polymer Science and Technology, Eastern Economy Edition, 1999.
5. Rodriguez, F., Cohen.C., Oberic.K and Arches, L.A., Principles of Polymer Systems,
5th edition, Taylor an

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